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  3. (+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane  (Synonyms: (S,S)-Ph-BPE)

Cat. No.: HY-W021016 Purity: ≥98.0%
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(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane ((S,S)-Ph-BPE) serves as a chiral phosphine ligand in the asymmetric hydrogenation of allylic sulfoxides, through a dynamic kinetic resolution process facilitated by Rh-catalyzed hydrogenation, utilizing insights from both theoretical and experimental mechanistic studies.

For research use only. We do not sell to patients.

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane Chemical Structure

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane Chemical Structure

CAS No. : 824395-67-7

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Description

(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane ((S,S)-Ph-BPE) serves as a chiral phosphine ligand in the asymmetric hydrogenation of allylic sulfoxides, through a dynamic kinetic resolution process facilitated by Rh-catalyzed hydrogenation, utilizing insights from both theoretical and experimental mechanistic studies.

Molecular Weight

506.60

Formula

C34H36P2

CAS No.
Appearance

Solid

Color

White to off-white

SMILES

P1([C@H](C2=CC=CC=C2)CC[C@H]1C3=CC=CC=C3)CCP4[C@H](C5=CC=CC=C5)CC[C@H]4C6=CC=CC=C6

Shipping

Room temperature in continental US; may vary elsewhere.

Storage

4°C, stored under nitrogen

*In solvent : -80°C, 6 months; -20°C, 1 month (stored under nitrogen)

Purity & Documentation

Purity: ≥98.0%

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(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane Related Classifications

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Product Name:
(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane
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HY-W021016
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